TRI-GAS INC -- OXYGEN -- 6830-00N043568
===================== Product Identification ===================== Product ID:OXYGEN MSDS Date:10/01/1991 FSC:6830 NIIN:00N043568 === Responsible Party === Company Name:TRI-GAS INC Address:4545 FULLER DRIVE SUITE 100 City:IRVING State:TX ZIP:75038 Country:US Info Phone Num:214-650-1700 Emergency Phone Num:214-650-1700 CAGE:0B434 === Contractor Identification === Company Name:TRI-GAS INC Address:4545 FULLER DRIVE SUITE 100 Box:City:IRVING State:TX ZIP:75038 Country:US Phone:214-650-1700 CAGE:0B434 ============= Composition/Information on Ingredients ============= Ingred Name:ING 15:COMPRESSED GAS CYLS SHOULD NOT BE REFILLED EXCEPT BY QUALIFIED PRODUCERS OF COMPRESSED GASES. SHIPMENT OF(ING 17) RTECS #:9999999ZZ Ingred Name:ING 16: COMPRESSED GAS CYL WHICH HAS NOT BEEN FILLED BY OWNER/WITH HIS (WRITTEN) CONSENT IS VIOLATION OF FED LAW(ING 18) RTECS #:9999999ZZ Ingred Name:ING 17: (49CFR). OXYGEN VIGOROUSLY ACCELERATES COMBUST. CONT W/ALL FLAMM MATLS SHOULD BE AVOIDED. SOME MATLS (ING 19) RTECS #:9999999ZZ Ingred Name:ING 18: WHICH ARE NOT FLAMMABLE IN AIR WILL BURN IN PURE OXYGEN OR OXYGEN-ENRICHED ATMOSPHERES. RTECS #:9999999ZZ Ingred Name:SOL IN H*2O:BUNSEN COEFFICIENT= 0.0310 RTECS #:9999999ZZ Ingred Name:SUPP DATA: FLUSH WITH WATER FOR AT LEAST 15 MINUTES . INGESTION: CALL MD IMMEDIATELY . RTECS #:9999999ZZ Ingred Name:OTHER PREC: CONNECTING CYL TO LOW PRESS (<3000 PSIG) PIPING/SYS. DO NOT HEAT CYL BY ANY MEANS TO INCR DISCHARGE (ING 4) RTECS #:9999999ZZ Ingred Name:ING 3: RATE OF PROD FROM CYL. USE CHECK VALVE/TRAP IN DISCHARGE LINE TO PVNT HAZ BACK FLOW INTO CYL. PROT CYLS (ING 5) RTECS #:9999999ZZ Ingred Name:ING 4: FROM PHYS DMG. STORE IN COOL, DRY, WELL-VENT AREA AWAY FROM HEAVILY TRAFFICKED AREAS & EMERG EXITS & AWAY (ING 6) RTECS #:9999999ZZ Ingred Name:ING 5: FROM FULL/EMPTY STORED CYLS WHICH CONTAIN FLAMM PRODS. DO NOT ALLOW TEMP WHERE CYLS ARE STORED TO EXCEED (ING 7) RTECS #:9999999ZZ Ingred Name:ING 6:130F (54C). CYLS SHOULD BE STORED UPRIGHT & FIRMLY SECURED TO PVNT FALLING/BEING KNOCKED OVER. FULL & EMPTY(ING 8) RTECS #:9999999ZZ Ingred Name:ING 7: CYLS SHOULD BE SEGREGATED. USE "FIRST IN-FIRST OUT" INVENTORY SYS TO PVNT FULL CYLS BEING STORED FOR (ING 9) RTECS #:9999999ZZ Ingred Name:ING 8: EXCESSIVE PERIODS OF TIME. CARBON STEELS & LOW ALLOY STEELS ARE ACCEPTABLE FOR USE AT LOWER PRESS. FOR (ING 10) RTECS #:9999999ZZ Ingred Name:ING 9: HIGH PRESS APPLIC USE STAINLESS STEELS, COPPER & ITS ALLOYS, NICKEL & ITS ALLOYS, BRASS, BRONZE, SILICON (ING 11) RTECS #:9999999ZZ Ingred Name:ING 10: ALLOYS, MONEL, INCONEL/BERYLLIUM. LEAD & SILVER/LEAD & TIN ALLOYS ARE GOOD GASKETING MATLS. TEFLON & (ING 12) RTECS #:9999999ZZ Ingred Name:ING 11: KEL-F ARE PREFERRED NONMETAL GASKETS. SPECIAL NOTE: IT SHOULD BE RECOGNIZED THAT IGNIT TEMP OF METALS & (ING 13) RTECS #:9999999ZZ Ingred Name:ING 12: NONMETALS IN PURE OXYGEN SERVICE DECREASES W/INCR OXYGEN PRESS. OXYGEN SHOULD NOT BE USED AS SUBSTITUTE (ING 14) RTECS #:9999999ZZ Ingred Name:ING 13: FOR COMPRESSED AIR IN PNEUMATIC EQUIP SINCE THIS TYPE GENERALLY CONTAINS FLAMM LUBRICANTS. EQUIP TO (ING 15) RTECS #:9999999ZZ Ingred Name:ING 14: CONTAIN OXYGEN MUST BE "CLEANED FOR OXYGEN SERVICE." SEE COMPRESSED GAS ASSOCIATION PAMPHLET G-4.1. (ING 16) RTECS #:9999999ZZ Ingred Name:OXYGEN CAS:7782-44-7 RTECS #:RS2060000 Fraction by Wt: 31.999% OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE LISTED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:BREATHING HIGH CONCENTRATIONS (GREATER THAN 75 MOLAR PERCENT) CAUSES SYMPTOMS OF HYPEROXIA WHICH INCLUDE CRAMPS, NAUSEA, DIZZINESS, HYPOTHERMIA, AMBYLOPIA, RESPIRATORY DIFFICULTIES, BRADYCARDIA, FAINT ING SPELLS AND CONVULSIONS CAPABLE OF LEADING TO DEATH. TOX PROPERTIES: THE PROPERTY IS THAT OF (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ:HYPEROXIA WHICH LEADS TO PNEUMONIA. CONCS BETWEEN 25 AND 75 MOLAR PERCENT PRESENT A RISK OF INFLAMMATION OF ORGANIC MATTER IN THE BODY. Medical Cond Aggravated by Exposure:NONE LISTED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:PROMPT MED ATTN IS MANDATORY IN ALL CASES OF OVEREXP TO OXYGEN. RESCUE PERS SHOULD BE COGNIZANT OF EXTREME FIRE HAZ ASSOC W/OXYGEN-RICH ATMOSPHERES. INHAL:CONSCIOUS PERSONS SHOULD BE ASSISTED TO AN UN CONTAM AREA & BRTHE FRESH AIR. THEY SHOULD BE KEPT WARM & QUIET. PHYS SHOULD BE INFORMED THAT VICTIM IS EXPERIENCING (HAS EXPERIENCED) HYPEROXIA. UNCON PERSONS SHOULD BE MOVED TO AN UNCONTAM (SUPDAT) ===================== Fire Fighting Measures ===================== Extinguishing Media:COPIOUS QUANTITIES OF WATER FOR FIRES WITH OXYGEN AS OXIDIZER. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . IF POSSIBLE, STOP FLOW OF OXYGEN WHICH IS SUPPORTING FIRE. Unusual Fire/Explosion Hazard:VIGOROUSLY ACCELERATES COMBUSTION. ================== Accidental Release Measures ================== Spill Release Procedures:EVAC ALL PERS FROM AFFECTED AREA. USE APPROP PROT EQUIP. IF LEAK IS IN USER'S EQUIPMENT, BE CERTAIN TO PURGE PIPING WITH AN INERT GAS PRIOR TO ATTEMPTING REPAIRS. IF LEAK IS IN CONTAINER OR CONTAINER VALVE, CONTACT CLOSEST TRI-GAS, INC LOCATION. Neutralizing Agent:NONE LISTED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:USE ONLY IN WELL-VENTILATED AREAS. Other Precautions:VALVE PROT CAPS & VALVE OUTLET THREADED PLUGS MUST REMAIN IN PLACE UNLESS CNTNR IS SECURED W/VALVE OUTLET PIPED TO USE POINT. DO NOT DRAG, SLIDE/ROLL CYLS. USE SUITABLE HAND TRUCK FOR CYL MOVEMENT. US E PRESS REDUCING REGULATOR WHEN (ING 3) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:LOCAL EXHAUST TO PREVENT ACCUMULATION ABOVE 25 MOLAR PERCENT. Protective Gloves:IMPERVIOUS GLOVES . Eye Protection:CHEMICAL SAFETY GOGGLES . Other Protective Equipment:SAFETY SHOES, SAFETY SHOWERS. Work Hygienic Practices:NONE LISTED BY MANUFACTURER. Supplemental Safety and Health VP: @ 70F (21.1C) ABOVE CRITICAL TEMP OF - 181,433F (-118,574C). WASTE DISP METH: I/A/W FED, ST,& LOC REGS . FIRST AID PROC: AREA & GIVEN ASSIST RESP. WHEN BRTHG HAS BEEN RESTORED, TREATMENT SHO ULD BE AS ABOVE. CONTINUED TREATMENT SHOULD BE SYMP & SUPPORTIVE. SKIN: FLUSH W/COPIOUS AMTS OF WATER . EYE:(ING 2 ================== Physical/Chemical Properties ================== HCC:D1 Boiling Pt:B.P. Text:-297F,-183C Melt/Freeze Pt:M.P/F.P Text:-362F,-119C Vapor Pres:SUPP DATA Spec Gravity:1.11 (AIR=1) Solubility in Water:(SEE ING 20) Appearance and Odor:COLORLESS, ODORLESS AND TASTELESS GAS. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ALL FLAMMABLE MATERIALS. Stability Condition to Avoid:NONE LISTED BY MANUFACTURER. Hazardous Decomposition Products:NONE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DO NOT ATTEMPT TO DISP OF RESIDUAL/UNUSED QTYS. RETURN TO SHIPPING CNTNR PROPERLY LBLD, W/ANY VALVE OUTLET PLUGS/CAPS SECURED & VALVE PROT CAP IN PLACE TO TRI-GAS, INC FOR PROPER DISP. FOR EMERG DISP, CONT CLOSEST TRI-GAS, INC LOCATION. DISP(SUPDAT) Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.