PRESTONE PRODUCTS CORP -- ANTIFREEZE/COOLANT, AF338 -- 6850-00N068568
===================== Product Identification ===================== Product ID:ANTIFREEZE/COOLANT, AF338 MSDS Date:12/02/1994 FSC:6850 NIIN:00N068568 === Responsible Party === Company Name:PRESTONE PRODUCTS CORP Address:83 WOOSTER HEIGHTS RD City:DANBURY State:CT ZIP:06813-1911 Country:US Info Phone Num:203-731-2300 Emergency Phone Num:800-424-9300 (CHEMTREC) CAGE:EO340 === Contractor Identification === Company Name:PRESTONE PRODUCTS CORPORATION Address:55 FEDERAL ROAD City:DANBURY State:CT ZIP:06810 Country:US Phone:203-830-7865 CAGE:EO340 ============= Composition/Information on Ingredients ============= Ingred Name:ETHYLENE GLYCOL (SARA 313) (CERCLA) CAS:107-21-1 RTECS #:KW2975000 Fraction by Wt: 80-95% OSHA PEL:50 PPM, C (MFR) ACGIH TLV:50 PPM, VAPOR, C EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:DIETHYLENE GLYCOL CAS:111-46-6 RTECS #:ID5950000 Fraction by Wt: 0-8% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:TOLYTRIAZOLE, SODIUM SALT; (TOLYTRIAZOLE) Fraction by Wt: <0.5% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 1-5% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:SUPDAT:AT HIGH CONCS/DOSES. IN PRELIMINARY STUDY, EFTS OF EXPOS OF PREGNANT RATS & MICE TO AEROSOLS, TERATOGENIC (ING 6) RTECS #:9999999ZZ Ingred Name:ING 5:EFTS WERE PRDCD AT HIGHEST CONC IN MICE. IN STUDY COMPARING EFTS FROM HIGH AEROSOL CONC BY WHOLE-BODY/NOSE-(ING 7) RTECS #:9999999ZZ Ingred Name:ING 6:ONLY EXPOS, NOSE-ONLY RSLTD IN MATERNAL & DEVEL TOX W/MIN EVID OF TERATOGENICITY. ING 3 HAS DEMONSTRATED (ING 8) RTECS #:9999999ZZ Ingred Name:ING 7:MUTAGENIC ACTIVITY IN BACTERIAL TEST SYS. PROD CNTNS TRACE LEVELS OF CHEMS WHICH THE STATE OF CALIFORNIA (ING 9) RTECS #:9999999ZZ Ingred Name:ING 8:HAS FOUND TO CAUSE CANCER &/OR BIRTH DEFECTS/OTHER REPRO HARM. CONTACT NEHC FOR MORE SPECIFIC INFO . RTECS #:9999999ZZ Ingred Name:FIRST AID PROC:STOPPED & SEEK IMED MED ATTN. EYES:IMMED FLUSH W/COPIOUS AMTS OF WATER. AFTER INITIAL FLUSHING, (ING 11) RTECS #:9999999ZZ Ingred Name:ING 10:REMOVE ANY CONTACT LENSES & CONTINUE FLUSHING FOR AT LST 15 MINS. IF IRRIT, PAIN/SWELL DEVELS, SEEK IMMED(ING 12) RTECS #:9999999ZZ Ingred Name:ING 11:MED ATTN. NOTES TO MD:PRINCIPAL TOX EFTS OF ING 1, WHEN SWALLOWED, ARE KIDNEY DMG & METABOLIC ACIDOSIS. (ING 13) RTECS #:9999999ZZ Ingred Name:ING 12:ETHANOL IS ANTIDOTAL & ITS EARLY ADMIN MAY BLOCK FORM OF NEPHROTOXIC METABOLITES OF ING 1 IN LIVER. THE (ING 14) RTECS #:9999999ZZ Ingred Name:ING 13:OBJECTIVE IS TO RAPIDLY ACHIEVE & MAINTAIN BLOOD ETHANOL LEVEL OF APPROX 100 MG/DL BY GIVING LOADING DOSE(ING 15) RTECS #:9999999ZZ Ingred Name:ING 14:OF ETHANOL FOLLOWED BY MAINT DOSE. IV ADMIN OF ETHANOL IS PREF RTE. HEMODIALYSIS MAY BE REQD. 4- (ING 16) RTECS #:9999999ZZ Ingred Name:ING 15:METHYLPYRAZOLE, POTENT INHIBITOR/ALCOHOL DEHYDROGENASE, HAS BEEN USED THERAPEUTICALLY TO DECR METABOLIC (ING 17) RTECS #:9999999ZZ Ingred Name:ING 16:CONSEQUENCES OF ING 1 POIS. ADDNL THERAPEUTIC MODALITIES WHICH MAY DECR ADVERSE CONSEQUENCES OF ING 1 (ING 18) RTECS #:9999999ZZ Ingred Name:ING 17:METABOLISM ARE ADMIN OF BOTH THIAMINE & PYRIDOXINE. PULM EDEMA W/HYPOXEMIA HAS BEEN DESCRIBED IN NUMBER (ING 19) RTECS #:9999999ZZ Ingred Name:ING 18:OF PATIENTS FOLLOWING POIS W/ING 1. NIOSH APPRVD RESP SUPPORT W/MECH VENT MAY BE REQD. THERE MAY BE (ING 20) RTECS #:9999999ZZ Ingred Name:ING 18:CRANIAL NERVE INVOLVEMENT IN LATE STAGES OF TOX FROM SWALLOWING ING 1. IN PARTICULAR, EFTS HAVE BEEN (ING 21) RTECS #:9999999ZZ Ingred Name:ING 20:REPORTED INVOLVING SEVENTH, EIGHTH & NINTH CRANIAL NERVES, PRESENTING BILATERAL FACIAL PARALYSIS, (ING 22) RTECS #:9999999ZZ Ingred Name:ING 21:DIMINISHED HEARING & DYSPHAGIA. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:ACUTE:INGEST:BITTER TASTE, ABDOM DISCOMFORT/PAIN, NAUS, VOMIT, DIZZ, MALAISE, BLURRING OF VISION, IRRITABILITY, FLANK PAIN, DECR IN URINE PROD & CNS EFTS; IRREG EYE MOVEMENTS, CONVLS & COMA. CARDIAC F AILURE & PULM EDEMA MAY DEVEL. LG VOLS OF ING 1:SEV KIDNEY DMG. MAY BE FATAL. DEVEL OF WEAK OF FACIAL (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ:MUSCLES, DIMINISHED HEARING & DFCLTY W/SWALLOWING DURING LAST STAGES OF SEV POIS. LIVER INJURY. INHAL:IRRIT OF NOSE & THROAT W/HDCH. HIGH VAP CONCS MAY PRDCE NAUS, VOMIT, HDCH, DIZZ & IRREG EYE MOVEMENTS. EYE:DISCOMFORT W/PERSISTENT CONJ. CHRONIC:INHAL MAY PRDCE CNS INVOLVEMENT, PARTICULARY DIZZ & (SUPP DATA) Medical Cond Aggravated by Exposure:MAY AGGRAVATE EXISTING KIDNEY DISEASE. ======================= First Aid Measures ======================= First Aid:INGEST:GET MED ASSISTANCE BY IMMED CALLING MD, EMER ROOM/POIS CTL CTR. IF ADVISE IS NOT AVAIL & VICTIM IS CONSCIOUS & ALERT IMMED INDUCE VOMIT. TAKE VICTIM & CNTNR TO NEAREST EMER ROOM. SKIN:REMOVE CO NTAM CLTHG & SHOES. IMMED WASH ALL AFFECTED & EXPOS AREAS W/SOAP & COPIOUS AMTS OF WATER, SEEK MD. INHAL:REMOVE TO FRESH AIR. IF BRTHG BECOMES DFCLT, ADMIN OXYG. ADMIN ARTF RESP IS BRTHG HAS (ING 10) ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:220F,104C Lower Limits:3.2% Upper Limits:15.3% Extinguishing Media:ALCOHOL/ALL-PURPOSE TYPE FOAMS BY MFR'S REC TECHNIQUES FOR LG FIRES. WATER SPRAY, CARBON DIOXIDE/DRY CHEM FOR SM FIRES. Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIP . DO NOT SPRAY POOL FIRES DIRECTLY. A SOLID STREAM OF WATER/FOAM DIRECTED INTO HOT BURNING LIQ CAN CAUSE FROTHING. Unusual Fire/Explosion Hazard:NONE. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR SUITABLE PROTECTIVE EQUIPMENT. SMALL SPILLS SHOULD BE FLUSHED W/LARGE QUANTITIES OF WATER. LARGER SPILLS SHOULD BE COLLECTED FOR DISPOSAL. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:DO NOT DRINK ANTIFREEZE OR SOLUTION. AVOID BREATHING VAPORS OR MISTS. DO NOT STORE IN OPEN OR UNLABELED CONTAINERS. KEEP OUT OF REACH OF CHILDREN. Other Precautions:KEEP CONTAINER AWAY FROM OPEN FLAMES & EXCESSIVE HEAT. DO NOT CUT OR WELD ON OR NEAR CONTAINER, EVEN EMPTY. DO NOT REUSE EMPTY CONTAINERS UNLESS PROPERLY CLEANED. OBSERVE ALL REQUIREMENTS OF PLANT, CO MPANY OR GOVERNMENT REGULATIONS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:FOR OPERATIONS WHERE TLV MAY BE EXCEEDED, NIOSH APPRVD RESP W/ORG VAP CARTRIDGE & DUST/MIST PREFILTER/SUPPLIED AIR RESP IS REC. EQUIP SELECTION DEPENDS ON CONTAM TYPE & CONC, SELECT I/A/W 29 CFR 1910. 134 & GOOD INDUS HYGIENE PRACTICE. Ventilation:GEN VENT SHOULD BE ADEQ FOR NORM USE AT AMBIENT TEMPS. FOR OPERATIONS WHERE MATL IS HEATED/MISTED & TLV MAY BE (SUPDAT) Protective Gloves:CHEM RESIST(NEOPRENE/PVC COATED) GLOVES. Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS . Other Protective Equipment:ANSI APPROVED EYE WASH FOUNTAIN & DELUGE SHOWER . PROT CLTHG IF NEEDED TO AVOID PROLONGED/REPEATED SKIN CONTACT. Work Hygienic Practices:WASH EXPOSED SKIN THORO W/SOAP & WATER AFTER USE. CONTAMINATED CLOTHING SHOULD BE REMOVED & LAUNDERED BEFORE RE-USE. Supplemental Safety and Health VENT:EXCEEDED, FORCED VENT SUCH AS LOC EXHST MAY BE NEEDED TO MAINTAIN EXPOS LEVELS BELOW APPLIC LIMS. EFTS OF OVEREXP:NYSTAGMUS. CONSTANT SKIN CONT MAY CAUSE SENSIT & ASSOC DERM IN SOME INDIVIDUALS. ING 1 HAS BEEN SHOWN TO PRDCE DOSE-RELATED TERATOGENIC EFTS IN RATS & MICE WHEN GIVEN BY GAVAGE/IN DRINKING WATER(ING 5) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:334F,168C Melt/Freeze Pt:M.P/F.P Text:-8F,-22C Vapor Pres:<0.1 @ 68F Vapor Density:2.1 Spec Gravity:1.13 Evaporation Rate & Reference:<1 (BUTYL ACETATE=1) Solubility in Water:100% BY WT Appearance and Odor:YELLOW; MILD ODOR. Percent Volatiles by Volume:NONE ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES AVOID STRONG BASES AT HIGH TEMPS, STRONG ACIDS, STRONG OXIDIZING AGENTS & MATLS REACTIVE W/HYDROXYL COMPOUNDS. Stability Condition to Avoid:NONE. Hazardous Decomposition Products:BURNING MAY PRODUCE CARBON MONOXIDE &/OR CARBON DIOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:INCINERATE IN A FURNACE WHERE PERMITTED UNDER APPROPRIATE FEDERAL, STATE OR LOCAL REGULATIONS. AT VERY LOW CONCENTRATION IN WATER, ETHYLENE GLYCOL IS READILY BIODEGRADABLE IN A BIOLOGICAL WASTEWATER T REATMENT PLANT. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.