PRESTONE PRODUCTS CORP -- AF777, PRESTONE ANTIFREEZE/COOLANT -- 6850-01-252-8501
===================== Product Identification ===================== Product ID:AF777, PRESTONE ANTIFREEZE/COOLANT MSDS Date:10/18/1999 FSC:6850 NIIN:01-252-8501 Status Code:A === Responsible Party === Company Name:PRESTONE PRODUCTS CORP Address:39 OLD RIDGEBURY RD City:DANBURY State:CT ZIP:06810-5109 Country:US Info Phone Num:203-731-3686/830-7865 Emergency Phone Num:(800)424-9300 Resp. Party Other MSDS Num.:MSDSP149 Preparer's Name:STAN PRUSAKOWSKI Chemtrec Ind/Phone:(800)424-9300 CAGE:0CXZ7 === Contractor Identification === Company Name:COMPTECH CORP Address:15944 DERWOOD RD Box:City:ROCKVILLE State:MD ZIP:20855 Country:US Phone:800-284-5279; 301-519-3401 Contract Num:SP0450-02-M-M103 CAGE:0BR38 Company Name:PRESTONE PRODUCTS CORP Address:39 OLD RIDGEBURY RD Box:City:DANBURY State:CT ZIP:06810-5109 Country:US Phone:203-731-3686/830-7865 CAGE:0CXZ7 ============= Composition/Information on Ingredients ============= Ingred Name:ETHYLENE GLYCOL (AEROSOL) CAS:107-21-1 RTECS #:KW2975000 Minumum % Wt:80. Maxumum % Wt:96. Other REC Limits:NOT PROVIDED ACGIH STEL:C127 MG/M3;C50 PPM EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:DIETHYLENE GLYCOL CAS:111-46-6 RTECS #:ID5950000 Minumum % Wt:0. Maxumum % Wt:8. Other REC Limits:NOT PROVIDED Ingred Name:NON-HAZARDOUS INGREDIENTS WATER CAS:7732-18-5 RTECS #:ZC0110000 > Wt:1. Other REC Limits:NOT PROVIDED Code:F Code:F ===================== Hazards Identification ===================== LD50 LC50 Mixture:NOT PROVIDED Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:INHALATION: MAY CAUSE IRRITATION OF NOSE AND THROAT. HIGH VAPOR CONCENTRATIONS MAY PRODUCE NAUSEA, VOMITING, HEADACHE, DIZZINESS AND IRREGULAR EYE MOVEMENTS. SKIN CONTACT: NO EVIDENCE OF ADVERSE EFFEC TS. EYE CONTACT: LIQUID, VAPOR OR MIST MAY CAUSE DISCOMFORT IN THE EYE WITH PERSISTENT CONJUNCTIVITIS. INGESTION: MAY CAUSE ABDOMINAL DISCOMFORT/PAIN, A BITTER TASTE, NAUSEA, VOMITING, DIZZINESS, DROW SINESS, MALAISE, BLURRING VISION, BACK PAIN, KIDNEY FAILURE. CARDIAC FAILURE, PULMONARY EDEMA, SEVERE KIDNEY AND LIVER DAMAGE MAY ALSO OCCUR. MAY BE FATAL. CHRONIC: CENTRAL NERVOUS SYSTEM INVOLVEMENT, SKIN SENSITIZATION, DERMATITIS. Explanation of Carcinogenicity:NONE OF THE COMPONENTS IN THESE PRODUCTS IS LISTED AS A CARCINOGEN OR SUSPECTED CARCINOGEN BY IARC, NTP OR OSHA. Effects of Overexposure:INHALATION: HIGH VAPOR CONCENTRATIONS MAY PRODUCE NAUSEA, VOMITING, HEADACHE DIZZINESS AND IRREGULAR EYE MOVEMENTS. INGESTED: ABDOMINAL DISCOMFORT/PAIN, A BITTER TASTE, NAUSEA, VOMITING, DIZZINESS, D ROWSINESS, MALAISE, BLURRING VISION, BACK PAIN. EYE CONTACT: REDNESS, CONJUNCTIVA, DISCOMFORT. Medical Cond Aggravated by Exposure:THE AVAILABLE TOXICOLOGICAL INFORMATION AND A KNOWLEDGE OF THE PHYSICAL AND CHEMICAL PROPERTIES OF THE MATERIAL SUGGEST THAT OVEREXPOSURE IS UNLIKELY TO AGGRAVATE EXISTING MEDICAL CONDITIONS. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE VICTIM TO FRESH AIR. IF BREATHING HAS STOPPED, ADMINISTER ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, HAVE MEDICAL PERSONNEL ADMINISTER OXYGEN. GET MEDICAL ATTENTION. SKIN: I MMEDIATELY WASH CONTACTED AREA THOROUGHLY WITH SOAP AND WATER. IF IRRITATION PERSISTS, GET MEDICAL ATTENTION. EYES: IMMEDIATELY FLUSH WITH LARGE AMOUNT OF WATER FOR 15 MINUTES. GET MEDICAL ATTENTION I F IRRITATION PERSISTS. INGESTION: SEEK IMMEDIATE MEDICAL ATTENTION. CALL POISON CONTROL CENTER. NEVER GIVE ANYTHING BY MOUTH TO OR INDUCE VOMITING IN AN UNCONSCIOUS OR DROWSY PERSON. ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:=104.4C, 220.F Autoignition Temp:Autoignition Temp Text:N/D Lower Limits:3.2 Upper Limits:15.3 Extinguishing Media:FOR LARGE FIRES, USE ALCOHOL TYPE OR ALL-PURPOSE FOAMS. FOR SMALL FIRES, USE WATER SPRAY, CARBON DIOXIDE OR DRY CHEMICAL. Fire Fighting Procedures:DO NOT SPRAY POOL FIRES DIRECTLY. COOL FIRE EXPOSED CONTAINERS WITH WATER. FIREFIGHTERS SHOULD WEAR POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING FOR FIRES IN AREAS WHERE CHEMICALS ARE USED OR STORED. Unusual Fire/Explosion Hazard:A SOLID STREAM OF WATER OR FOAM DIRECTED INTO HOT, BURNING LIQUID CAN CAUSE FROTHING. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR APPROPRIATE PROTECTIVE CLOTHING AND EQUIPMENT. COLLECT WITH ABSORBENT MATERIAL AND PLACE IN APPROPRIATE, LABELED CONTAINER FOR DISPOSAL OR, IF PERMITTED FLUSH SPILL AREA WITH WATER. Neutralizing Agent:NOT PROVIDED ====================== Handling and Storage ====================== Handling and Storage Precautions:DO NOT STORE IN OPENED OR UNLABELED CONTAINERS. KEEP CONTAINERS AWAY FROM OPEN FLAMES AND EXCESSIVE HEAT. DO NOT REUSE EMPTY CONTAINERS UNLESS PROPERLY CLEANED. USE OF THIS PRODUCT IN ELEVATED TEMPERA TURE APPLICATIONS SHOULD BE THOROUGHLY EVALUATED TO ASSURE SAFE OPERATIONS. Other Precautions:DO NOT DRINK ANTIFREEZE OR SOLUTION. AVOID EYE AND PROLONGED OR REPEATED SKIN CONTACT. AVOID BREATHING VAPORS OR MISTS. WASH EXPOSED SKIN THOROUGHLY WITH SOAP AND WATER AFTER USE. EMPTY CONTAINERS RET AIN PRODUCT RESIDUES AND MAY BE DANGEROUS. DO NOT CUT, WELD, DRILL, ETC. CONTAINERS, EVEN EMPTY. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF THE TLV IS EXCEEDED A NIOSH APPROVED RESPIRATOR WITH ORGANIC VAPOR CARTRIDGE AND DUST/MIST PREFILTERS OR SUPPLIED AIR RESPIRATOR IS RECOMMENDED. EQUIPMENT SELECTION DEPENDS ON CONTAMINANT TYPE AND CONCENTRATION. SELECT AND USE IN ACCORDANCE WITH 29 CFR 1910.134 AND GOOD INDUSTRIAL HYGIENE PRACTICE. FOR FIREFIGHTING, USE SELF-CONTAINED BREATHING APPARATUS. Ventilation:USE GENERAL VENTILATION OR LOCAL EXHAUST AS REQUIRED TO MAINTAIN EXPOSURES BELOW THE OCCUPATIONAL EXPOSURE LIMITS. Protective Gloves:CHEMICAL RESISTANT GLOVES SUCH AS NEOPRENE OR PVC WHERE CONTACT IS POSSIBLE. Eye Protection:SPLASH-PROOF GOGGLES. Other Protective Equipment:APPROPRIATE PROTECTIVE CLOTHING AS NEEDED TO MINIMIZE SKIN CONTACT. SUITABLE WASHING AND EYE FLUSHING FACILITIES SHOULD BE AVAILABLE IN THE WORK AREA. Work Hygienic Practices:CONTAMINATED CLOTHING SHOULD BE REMOVED AND LAUNDERED BEFORE RE-USE. Supplemental Safety and Health ABBREVIATION: N/A = NOT APPLICABLE. N/AV = NOT AVAILABLE. N/K = UNKNOWN. N/P = NOT PROVIDED. N/R = NOT RELEVANT. N/D = NOT DETERMINED. N/E = NOT ESTABLISHED. CNS = CENTRAL NERVOUS SYSTEM. GI = GASTROI NTESTINAL. SCBA = SELF CONTAINED BREATHING APPARATUS. ================== Physical/Chemical Properties ================== HCC:V5 NRC/State Lic Num:NOT RELEVANT Boiling Pt:=167.8C, 334.F Melt/Freeze Pt:=-22.2C, -8.F Decomp Temp:Decomp Text:NOT PROVIDED Vapor Pres:<0.1 Vapor Density:2.1 Spec Gravity:1.12 pH:NOT DETERMINED Viscosity:NOT DETERMINED. Evaporation Rate & Reference:<1 Solubility in Water:COMPLETE (100%) Appearance and Odor:YELLOW LIQUID WITH A MILD ODOR. Percent Volatiles by Volume:NONE Corrosion Rate:NOT PROVIDED ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NORMALLY UNREACTIVE. HOWEVER, AVOID STRONG BASES AT HIGH TEMPERATURES, STRONG ACIDS, STRONG OXIDIZING AGENTS AND MATERIALS REACTIVE WITH HYDROXYL COMPOUNDS. Stability Condition to Avoid:NONE KNOWN. Hazardous Decomposition Products:BURNING MAY PRODUCE CARBON MONOXIDE AND CARBON DIOXIDE. =================== Toxicological Information =================== Toxicological Information:ETHYLENE GLYCOL LD50 ORAL RAT: 4700 MG/KG. LD50 SKIN RABBIT: 9530 MG/KG. DIETHYLENE GLYCOL: LD50 ORAL RAT: 12,565 MG/KG AND LD50 SKIN RABBIT: 11890 MG/KG. ETHYLENE GLYCOL HAS BEEN SHOWN TO PRODUCE DOS E-RELATED TERATOGENIC EFFECTS IN RATS AND MICE WHEN GIVEN IN DRINKING WATER AT HIGH CONCENTRATIONS OR DOSES. ===================== Ecological Information ===================== Ecological:ETHYLENE GLYCOL: LC50 GOLDFISH: 5,000 MG/L/24 HR, AT 20C STATIC CONDITIONS. TOXICITY THRESHOLD: BACTERIAL (PSEUDOMONAS PUTIDA): 10,000 MG/L; PROTOZOA: >10,000 MG/L; ALGAE: 2,000 MG/L; GREEN ALGAE: >10 ,000 MG/L. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF PRODUCT IN ACCORDANCE WITH ALL LOCAL, STATE/PROVINCIAL AND FEDERAL REGULATIONS. =================== MSDS Transport Information =================== Transport Information:DOT HAZARD CLASSIFICATION: NONE. IMDG: NOT REGULATED. NOTE IF BULK SHIPMENT IS INVOLVED, THE FOLLOWING INFORMATION APPLIES: US DOT PROPER SHIPPING NAME: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N. O.S. (ETHYLENE GLYCOL), 9, UN3082. ===================== Regulatory Information ===================== SARA Title III Information:EPA SARA 311/312: HAZARD CLASSIFICATION: ACUTE HEALTH AND CHRONIC HEALTH. EPA SARA 313: THIS PRODUCT CONTAINS THE FOLLOWING CHEMICALS SUBJECT TO ANNUAL RELEASE REPORTING REQUIREMENTS UNDER SARA TITLE III, SECTION 313 (40 CFR 372): ETHYLENE GLYCOL, CAS# 107-21-1, 80-96%. CERCLA SECTION 103: SPILLS OF THIS PRODUCT OVER THE RQ (REPORTABLE QUANTITY) MUST BE REPORTED TO THE NATIONAL RESPONSE CENTER. TH E RQ FOR THIS PRODUCT, BASED ON THE RQ FOR ETHYLENE GLYCOL (96% MAXIMUM) OF 5,000 LBS, IS 5,208 LBS. MANY STATES HAVE MORE STRINGENT RELEASE REPORTING REQUIREMENTS. REPORT SPILLS REQUIRED UNDER FEDERA L, STATE, AND LOCAL REGULATIONS. Federal Regulatory Information:EPA TSCA INVENTORY: ALL OF THE COMPONENTS OF THIS MATERIAL ARE LISTED ON THE TOXIC SUBSTANCE CONTROL ACT (TSCA) CHEMICAL SUBSTANCES INVENTORY. State Regulatory Information:CALIFORNIA PROPOSITION 65: THIS PRODUCT MAY CONTAIN THE FOLLOWING SUBSTANCES KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER AND/OR REPRODUCTIVE HARM: 1,4-DIOXANE (TRACE AMOUNT). ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.